| Name: |
Advanced Chemical Engineering Thermodynamics |
| Catalog Number: |
421003Y |
Hours/Credits: |
40/2 |
| Prerequisite(s): |
|
Advanced Mathematics; Physical Chemistry; Chemical Thermodynamics. |
| Course Description: |
|
This is basic disciplinary course for Master degree graduate student major in chemical engineering and technology. After completed course the student shall: able to gain the macroscopic properties from the interactions between micro molecules; able to calculate equilibrium properties of various components, especially the properties of fluids. Then, enhance the ability to solve engineering problems by applying chemical thermodynamics during researches and works on dissertations, and raise the academic levels of the scientific papers. |
| Course Content: |
|
Chapter 1 Fluid Thermodynamics
Fundamentals of thermodynamics; Fugacity and fugacity coefficient; Activity and activity coefficient; Permeation pressure and coefficient of permeability; Deviation function; Excess function; Equilibrium and stability criterion
Chapter 2 Fundamentals of statistical thermodynamics
Preliminary knowledge; Microcanonical ensemble; Canonical ensemble; Grand canonical ensemble; Fluctuation theory; Molecular partition function; Thermodynamic properties of ideal gas
Chapter 3 Intermolecular force and potential function
Intermolecular force; Potential energy function
Chapter 4 p-V-T relationship and equation of state of fluids
p-V-T properties of pure substances; EOS of ideal gas; EOS of hard-sphere fluid; Cubic equation of state; Multi-parameter equation of state; Virial equation of state; Reduced equation of state and its applications; Saturated thermodynamic properties of fluids; Mixing rule
Chapter 5 Non electrolyte solution theory,
Regular solution theory; Quasi-lattice model theory; Cell model theory; Wohl equation; Local component type equations; Group contribution type equation; Infinite dilution activity coefficient.
Chapter 6 Integral equation theory and perturbation theory;
Radial distribution function; Relation between thermodynamic function of fluid and radial distribution function; Ornstein-zernike equation; Perturbation theory; Statistical associating fluid theory
Chapter 7 Electrolyte solution theory
Debye-Hücker theory; Stokes-Robinson Ion hydration theory; Pitzer electrolyte solution theory; NRTL equation of electrolyte
Chapter 8 Phase equilibria and chemical equilibria
Formula of phase equilibria; Gas-liquid equilibria; Liquid-liquid equilibria; Solid-liquid equilibria; Gas-solid equilibria; Chemical equilibria
Chapter 9 Thermodynamic analysis of processes
Ideal work; Lost work;Tthermodynamic analysis of steady flow process; Work of separation process |
| TextBooks: |
|
|
| Reference: |
|
1 Ying Hu，Fluid molecular thermodynamics, Higher Education Press，1982 (in Chinese)
2 Yiyao Li, Jiufang Lu, The Theory of Electrolyte Solution。Tsinghua University Publishing House，2005 (in Chinese)
3 Ying Hu, Guojie Li, Yingnian Xu, Ziming Tan, Application statistical mechanics—research basis of fluid physical property, Chemical Industry Press, Beijing, 1990 (in Chinese)
4 McQuarrie D A. Statistical Mechanics, Harper & Row, New York, 1976 |
